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Key Points

4 points
1

Heat transport combines particle‑like phonon propagation with wave‑like coherence.

2

Copper atoms exhibit localized dynamic disorder rather than long‑range migration.

3

First‑principles calculations and molecular‑dynamics simulations revealed the mechanism.

4

Potential applications include thermoelectric generators and advanced thermal‑management technologies.

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Summary

The confined motion of copper atoms creates strong anharmonicity, allowing phonon coherence to dominate heat flow.

This results in a thermoelectric figure of merit of 1.7, making the material one of the most efficient for converting waste heat to electricity.

The discovery could improve energy recovery in power plants, steel factories, automobiles and data centres.

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New Words to Learn

13 words
crystalline
having a regular, repeating internal structure of atoms
thermoelectric
the direct conversion of temperature differences into electric voltage
phonon
a quantized unit of vibrational energy that carries heat in solids
anharmonicity
deviation from perfectly regular atomic vibrations, leading to irregular motion
coherence
the synchronized alignment of wave phases that allows them to reinforce each other
tetragonal
a crystal system shaped like a stretched cube with a square base
ternary
a compound made from three different chemical elements
chalcogenide
a class of materials containing elements from the chalcogen group such as sulfur, selenium, or tellurium
superionic
a state where certain ions move freely within a solid, similar to a liquid
molecular-dynamics
a computer simulation technique that models the physical movements of atoms and molecules over time
first-principles
computational methods that start from basic physical laws without empirical parameters
lattice
the orderly three‑dimensional arrangement of atoms in a crystal
thermal conductivity
a measure of how quickly heat can travel through a material
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